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Lecture 4: de Broglie matter waves, Group velocity and stationary phase, Free particle waves
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Lecture 4: de Broglie matter waves, Group velocity and stationary phase, Free particle waves
Wave particle duality (1924)
de Broglie associated a free particle with momentum pp to a plane wave with wavelength λ=hp\lambda=\frac{h}{p}, where hh is Planck’s constant. This relation only works in the quantum world since it is dependent on hh, which doesn’t exist in classical theory.
The momentum of the photons pphotonp_{photon}, is equal to E/cE/c, since it is massless. On the other hand, EgammaE_{gamma}, the energy of the photon, is given by hνc\frac{h \nu}{c}. Since the velocity of light is cc, we have Egamma=hλE_{gamma}=\frac{h}{\lambda}.
We can define the wave as ψ(x,t)C\psi(x,t)\in\mathbb{C}, with p=hλ=h2π2πλ=kp=\frac{h}{\lambda}=\frac{h}{2\pi}*\frac{2\pi}{\lambda}=\hbar k, where kk is the wavenumber. When we consider wave phenomena, a good question to ask is how a wave looks to different observers.
So we will consider two different observers in two frames of reference SS and SS’. Denote vv the velocity which the frame SS’ is moving with respect to the frame SS. The frames are arranged in such a way that the origins coincide at zero time. For simplicity, we relate them by a Galilean transformation. Given a point xx’, we have the relation to its other frame xx by x=xvtx’=x-vt, t=tt’=t.
We want to check if the two frames agree on the wavelength of the observed wave. If it is equal for both frames, what does it imply? hmm
To do this, we assume a particle is moving at v~>0\tilde v>0 in the SS frame. The momentum of this particle will thus be p=mv~>0.λ=hpp=m\tilde v>0. \\ \lambda=\frac{h}{p}.
In frame SS’, v~=dxdt=ddt(xvt)=v~v\tilde v’=\frac{dx’}{dt}=\frac{d}{dt}(x-vt)=\tilde v-v. p=mv~=m(v~v)=pmvp’=m\tilde v'=m(\tilde v-v)=p-mv. Therefore, we conclude the momentum in the frame SS' differs substantially different from the momentum in the frame SS. This implies the wavelengths also are rather different mathematically.
In our daily lives, ordinary measurable waves like waterwaves or soundwaves don’t transform under different frames of observers. This is partial evidence that these types of waves are not directly measurable, and ψ\psi, again is not a property that can be directly observed in an experiment.